I just discovered this great podcast site called "Nolo: Your Legal Companion." They are not, of course, designed for a library; however, there is lots of great stuff on there. There are segments on all kinds of different issues: how to sell a business, how to advocate for a special education child, how to discipline an employee, etc.
You can even submit a question (or comment). I don't know how many questions they get or what their policy is about doing a feed on different issues, but I did send a question off that I really hope they turn into a segment in the near future.
You can subscribe to Nolo through itunes or an RSS feed. Pretty cool, huh?
If you know of any other great legal-issues questions / podcasts, please let us know by commenting.